Beckmann rearrangement of aldoximes catalyzed by transition metal salts: A dehydration‐hydration reaction
- 1 January 1976
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 95 (5) , 123-125
- https://doi.org/10.1002/recl.19760950511
Abstract
The Beckmann rearrangement of aldoximes catalyzed by transition metal salts like palladium and nickel acetylacetonates is shown to be a dehydration‐hydration reaction in which the anti‐oxime is converted into nitrile and the nitrile is converted into amide.Keywords
This publication has 4 references indexed in Scilit:
- Synthesis of Nitriles. Use ofN-Ethylacetonitrilium Fluoroborate for Aldoxime DehydrationSynthesis, 1975
- Novel aryl cyanide synthesis using trichloroacetonitrileThe Journal of Organic Chemistry, 1973
- A Facile Synthesis of anti-BenzaldoximeSynthesis, 1972
- Isomerization of Aldoximes to Amides under Substantially Neutral Conditions1Journal of the American Chemical Society, 1961