Selective Detection in Gas Chromatography by Active Nitrogen-Induced Chemiluminescence
- 1 July 1980
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 34 (4) , 434-437
- https://doi.org/10.1366/0003702804731366
Abstract
Previous work has clearly shown that metastable transfer emission spectrometry has useful applications as a general detector for hydrocarbon gas chromatography and as a detector for organometallic compounds. We report here additional progress in determining the characteristics of the system response to HCl catalyzed chemiluminescence from saturated hydrocarbons and to oxygen-containing compounds. The implications in terms of a multipurpose general and selective detector for chromatography are discussed.Keywords
This publication has 9 references indexed in Scilit:
- Chemiluminescence detector based on active nitrogen for gas chromatography of hydrocarbonsAnalytical Chemistry, 1979
- Determination of trace amounts of alkyls and hydrides by metastable transfer emission spectrometryAnalytical Chemistry, 1978
- Analytical photon catalysis: Measurement of gas phase concentrations to 104/cm3Applied Physics Letters, 1977
- CN production efficiencies from active nitrogen-hydrocarbon flamesIEEE Journal of Quantum Electronics, 1976
- A Critical Review of the Gas-Phase Reaction Kinetics of the Hydroxyl RadicalJournal of Physical and Chemical Reference Data, 1972
- Hydroxyl Radical Kinetics by Kinetic Spectroscopy. VI. Reactions with Alkanes in the Range 300–500°KThe Journal of Chemical Physics, 1970
- HCl-Catalyzed Reaction of Hydrocarbons with Active NitrogenThe Journal of Chemical Physics, 1964
- Competitive chlorination reactions in the gas phase: hydrogen and C1—C5saturated hydrocarbonsTransactions of the Faraday Society, 1959
- THE REACTION OF NITROGEN ATOMS WITH METHANE AND ETHANECanadian Journal of Chemistry, 1951