Photoelectron spectra of metal tetrahydroborates
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1755-1761
- https://doi.org/10.1039/dt9780001755
Abstract
Helium-(I) and -(II) excited photoelectron spectra of the metal tetrakis(tetrahydroborates) M(BH4)4(M = Zr, Hf, or U) and the He(I) spectrum of Al(BH4)3 are reported. A simple molecular-orbital model is developed to account for features in the spectra associated with ligand ionizations. Final-state structure and cross-section variations for the outermost metal f subshells in U(BH4)4 and Hf(BH4)4 are discussed in relation to the expected atomic behaviour.Keywords
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