Level crossings and branch points studied by the multidimensional partitioning technique
- 1 May 1978
- journal article
- research article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 13 (5) , 619-626
- https://doi.org/10.1002/qua.560130506
Abstract
The possibility of level crossings is discussed from a general multidimensional partitioning viewpoint. By extending the traditional motion of a self‐adjoint Hamiltonian to a self‐adjoint analytic family of operators, it is found that level intersections that appear fall into two mutually exclusive categories: the conventional diagonal one corresponding to Jordan blocks of order m = 1, and the nondiagonal one with m ≥ 2. Consequences with respect to some recent examples, such as Longuet‐Higgins “sign‐reversing loop” construction and the 1II near degeneracy in SiO, are discussed and examined.Keywords
This publication has 16 references indexed in Scilit:
- Spectroscopic constants and radiative lifetimes for valence-excited bound states in SiOThe Journal of Chemical Physics, 1976
- Analytic structure of the eigenvalue problem as used in semiclassical theory of electronically inelastic collisionsThe Journal of Chemical Physics, 1976
- Real and complex intersections between potential energy surfaces of the same symmetry in polyatomic systemsChemical Physics Letters, 1975
- Ab initio calculations of potential energy surfaces in the complex plane. I. General theory and one-electron exampleThe Journal of Chemical Physics, 1973
- On the non-crossing rule for potential energy surfaces of polyatomic moleculesChemical Physics Letters, 1972
- The non‐crossing rule in molecular quantum mechanicsInternational Journal of Quantum Chemistry, 1972
- Diabatic and Adiabatic Representations for Atomic Collision ProblemsPhysical Review B, 1969
- Intersection of potential energy surfaces in polyatomic moleculesDiscussions of the Faraday Society, 1963
- Studies in perturbation theoryJournal of Molecular Spectroscopy, 1963
- Elementary Relativistic Wave Mechanics of Spin 0 and Spin 1/2 ParticlesReviews of Modern Physics, 1958