Statistical Mechanics of a Simple Entanglement
- 15 February 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (4) , 1475-1483
- https://doi.org/10.1063/1.1840877
Abstract
It is shown that the statistical mechanics of an entanglement produced by looping a polymer chain around an infinitely long straight bar can be treated exactly, essentially because successive turns of the chain around the bar can be considered as constituting a Markoff process. The elastic response of such a loop to a force exerted on one of its segments is nonlinear and surprisingly complex.Keywords
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