anti-Stereospecificity in the palladium-catalysed reactions of alkenyl- or aryl-metal derivatives with allylic electrophiles
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 160-161
- https://doi.org/10.1039/c39820000160
Abstract
Palladium-catalysed alkenyl–allyl or aryl–allyl cross-coupling, such as the reaction of the alkenylalane (1) with (2), can proceed with nearly complete (98%) inversion of configuration at participating allylic carbon centre.Keywords
This publication has 0 references indexed in Scilit: