Xanthates of titanium(III)
- 1 January 1970
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 23 (3) , 469-473
- https://doi.org/10.1071/ch9700469
Abstract
The first xanthates of titanium have been prepared from cp2TiCl (cp = π-cyclo-pentadienyl) and NaS2COR (R = CH3, C2H2, n-C3H7, n-C4H9, and n-C5H11) in air-free water under inert atmosphere. The trivalent titanium complexes are blue in colour, monomeric, and extremely sensitive to oxygen, with one unpaired electron per titanium atom. They are believed to be of the form (See diagram in article) with bidentate xanthato ligands, analogous to the corresponding dithiocarbamates.Keywords
This publication has 0 references indexed in Scilit: