Vibrational analysis of (SCN)2 and the transient (SCN)2−
- 15 October 1979
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 71 (8) , 3326-3329
- https://doi.org/10.1063/1.438774
Abstract
The vibrational spectra of thiocyanogen and the transient radical anion (SCN)2− are interpreted in detail through molecular orbital and normal coordinate calculations. The results support the assignment of (SCN)2− to the anion of thiocyanogen and indicate a substantial weakening of the S–S and C≡N bonds in going from the parent molecule to its radical anion.Keywords
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