Synthesis and characterisation of an alumina–supported RuOs3cluster catalyst
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 342-343
- https://doi.org/10.1039/c39830000342
Abstract
The alumina-supported anion cluster Al+[H3RuOs3(CO)12]– was formed by heating [H2RuOs3(CO)13] absorbed on γ-Al2O3 to 373–473 K under an H2+ CO atmosphere; the material is catalytically active for ethylene hydrogenation at 340 K and for but-1-ene isomerization at 330 K.Keywords
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