The Wittig-Horner reaction on 2,3,4,6-tetra-O-benzyl-D-mannopyranose and 2,3,4,6-tetra -O-benzyl-D-glucopyranose
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 7,p. 1281-1283
- https://doi.org/10.1039/p19890001281
Abstract
The synthetic utility of the Wittig-Horner reaction in the synthesis of C-glycosides is illustrated by the preparation of the α-and β-glycosyl acetates of the 2,3,4,6-tetra-O-benzyl-D-mannopyranose and of the 2,3,4,6-tetra-O-benzylglucopyranose. A partial epimerization of the C-2 carbon of the starting protected carbohydrate is observed.This publication has 2 references indexed in Scilit:
- Synthesis of C-glycosyl compounds by the wittig iodocyclization procedure. Differences from mercuriocyclizationCarbohydrate Research, 1987
- Two total syntheses of showdomycin and related studiesThe Journal of Organic Chemistry, 1986