Palladium Carbenoids from Enolates of α-Sulfonyl ε-Acetylenic Esters, Nitriles or Ketones : Evidence for the Existence of these Intermediates.

Abstract
The existence of a vinyl palladium carbenoid is proved by a set of reactions previously described for other types of carbenoids : dimerization, cyclopropanation, intramolecular capture by a keto group, addition of an alkaline sulfinate.

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