Reactions of fatty cyclopropenoids with hydrogen halides and halogens
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1750-1754
- https://doi.org/10.1039/p19720001750
Abstract
The additions of hydrogen halides and halogens to the cyclopropenoid ring of methyl sterculate have been shown to produce ring-opened and/or cyclopropanoid compounds. The composition of the products of these reactions has been determined quantitatively by n.m.r. and oxidative techniques. It is suggested that ring-opened compounds are formed by polar addition whereas halogenocyclopropanoids are produced by radical addition.Keywords
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