Modification of chemical properties of iron cyanides in solid solutions
- 1 January 1968
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 21 (9) , 2175-2188
- https://doi.org/10.1071/ch9682175
Abstract
The ions [Fe(CN)64-, [Fe(CN)63-, and [Fe(CN)5NO]2- have been incorporated as solid solutions in alkali-halide host lattices. For the hexacyanides, the CN stretch frequency is split in a manner which can be explained from C2v or D2h symmetry of the point defects introduced in the solid solutions. There is evidence of reduced species formed from [Fe(CN)6]3- and [Fe(CN)5NO]2-.Keywords
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