A single stranded diruthenium(II) helical complex
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 621-622
- https://doi.org/10.1039/c39900000621
Abstract
2,2′:6′,2″:6″2‴:6‴,2â�—-Quinquepyridine (qpy) forms a binuclear complex [(tpy)Ru(qpy)Ru(tpy)Cl][PF6]3(tpy = 2,2′:6′,2″-terpyridine) which has been structurally characterised and shown t o possess a helical structure with two six-co-ordinate ruthenium centres bridged by the qpy ligand; the complex is electrochemically active, but there are no significant interactions between the two metal centres.Keywords
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