Chiral discrimination in the oxidation of ferrocenes by cytochrome c peroxidase
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 6,p. 517-518
- https://doi.org/10.1039/a700243b
Abstract
Cytochrome c peroxidase shows a two-fold difference in its reaction rate with enantiomers of a chiral ferrocene; the enantiomeric selectivity is reversed by a single site specific change in the surface charge of the enzyme.Keywords
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