Enantioselective deprotonation reactions using a novel homochiral magnesium amide base
- 7 March 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 6,p. 479-480
- https://doi.org/10.1039/b000425l
Abstract
A novel homochiral magnesium bisamide base system has been prepared and reacted with a series of prochiral ketones in the presence of TMSCl to give efficient formation of the corresponding enol ethers in enantiomeric ratios of up to 95∶5.Keywords
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