Amine Elimination Reactions between Homoleptic Silylamide Lanthanide Complexes and an Isopropylidene-Bridged Cyclopentadiene−Fluorene System
- 18 June 2002
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 21 (15) , 3238-3249
- https://doi.org/10.1021/om0200398
Abstract
No abstract availableKeywords
This publication has 27 references indexed in Scilit:
- Synthesis and Olefin Polymerization Catalysis of New Trivalent Samarium and Yttrium Complexes with Bridging Bis(cyclopentadienyl) LigandsOrganometallics, 2001
- Synthesis and Olefin Polymerization Catalysis of New Divalent Samarium Complexes with Bridging Bis(cyclopentadienyl) LigandsOrganometallics, 1998
- Single site polymerization of ethylene and 1‐olefins initiated by rare earth metal complexesMacromolecular Chemistry and Physics, 1996
- Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in SolutionJournal of the American Chemical Society, 1994
- Iso-specific Ziegler-Natta polymerization of .alpha.-olefins with a single-component organoyttrium catalystJournal of the American Chemical Society, 1992
- Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalystOrganometallics, 1990
- Molecular hydrogen complexes. 6. The barrier to rotation of .eta.2-H2 in M(CO)3(PR3)2(.eta.2-H2) (M = tungsten, molybdenum; R = cyclohexyl, isopropyl): inelastic neutron scattering, theoretical, and molecular mechanics studiesJournal of the American Chemical Society, 1990
- Ethylene insertion and .beta.-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethyleneJournal of the American Chemical Society, 1990
- Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligandsJournal of the American Chemical Society, 1985
- Organolanthanides in catalysisAccounts of Chemical Research, 1985