Substituted tris(silyl)amines. Part III. 1-Trimethylsilyl-2,2,4,4-tetramethylcyclodisilazane
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 808-810
- https://doi.org/10.1039/j19690000808
Abstract
The title compound (I) was prepared by ammonolysis of Me3Si·N(SiMe2Cl)2 and characterised. It rearranges in the presence of acids or bases to give principally [Me3Si·NH·Si(Me2)·N·SiMe2]2(III). Hydrolysis gave [Me3Si·N·Si(Me2)·O·SiMe2]2(V). Cyclodisilazanes are opened by methyl-lithium.Keywords
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