Experiments on the synthesis of tetracycline. Part XI. Oxidation of ketone acetals and ethers by hydride transfer
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- Vol. 4, 542-552
- https://doi.org/10.1039/p19720000542
Abstract
A method for oxidising a diol as its acetonide, or other acetal, by hydride transfer to the triphenyl carbonium ion, is described. Triphenylcarbonium ion oxidation is applied to the selective deprotection of benzyl and benzyloxy-carbonyl ethers.Keywords
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