Determination of ruthenium(III) and palladium(II) in mixtures by derivative spectrophotometry
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in The Analyst
- Vol. 108 (1293) , 1506-1510
- https://doi.org/10.1039/an9830801506
Abstract
This paper describes a sensitive method for the determination of ruthenium(III) and palladium(II) in mixtures (up to 16 µg ml–1 of ruthenium and 4.5 µg ml–1 of palladium) by first and second derivative spectrophotometry. The method is based upon the coloured complexes that both ruthenium and palladium form with 2-thiobarbituric acid. A statistical analysis of the experimental results is presented.Keywords
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