Stereochemistry of C-1 hydrogen exchange in the interconversion of trans,trans- and cis,trans-farnesols by soluble enzymes from tissue cultures of Andrographis paniculata
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 385-386
- https://doi.org/10.1039/c39740000385
Abstract
When a cell-free system from A. paniculata tissue cultures isomerises trans,trans-farnesol (tt-F) to cis,trans-farnesol (ct-F), the 1-pro-R hydrogen of tt-F is retained and the 1-pro-S hydrogen lost; by contrast, conversion of ct-F proceeds with retention of the 1-pro-S and loss of the 1-pro-R hydrogen of ct-F.Keywords
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