Fluxional ligand migrations in triosmium clusters containing 2-pyridylphosphines
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 844-846
- https://doi.org/10.1039/c39930000844
Abstract
The cluster [Os3(CO)10(µ-L)](L = Ph2PC5H4N)(X-ray structure reported), containing the diaxially coordinated 2-pyridyldiphenylphosphine bridge, undergoes rapid transfer of the pyridine between two metal atoms while the phosphorus atom remains firmly coordinated to the third.Keywords
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