Perturbation theory, the mean spherical approximation, and the electrical double layer
- 1 July 1981
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 59 (13) , 1903-1905
- https://doi.org/10.1139/v81-283
Abstract
Simple arguments, based on perturbation theory, are used to derive expressions for the energy of a bulk ionic fluid and the potential difference in an electric double layer. These expressions are identical to those obtained from the much more elaborate mean spherical approximation.Keywords
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