The liquid hydrogen chloride solvent system. Part IX. Oxidation of some phosphorus(III) compounds
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1096-1098
- https://doi.org/10.1039/j19670001096
Abstract
The reactions of the halogens and related compounds with phosphorus(III) compounds in liquid hydrogen chloride have been investigated. Where oxidation occurred phosphorus was oxidised from the + 3 to the +5 oxidation state. The reactions were followed conductimetrically wherever possible. Evidence was obtained for the existence of the ions PCl3Br+ and Ph3PCl+ by stabilising them as the tetrachloroborate salts.Keywords
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