Stereoselective introduction of hydroxy-groups into the 24-, 25-, and 26-positions of the cholesterol side chain
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 115-117
- https://doi.org/10.1039/c39810000115
Abstract
Asymmetric reduction of steroidal 25-en-24-ones by a complex of LiAlH4 and 2,2′-dihydroxy-1,1′-binaphthyl led to a steroselective introduction of hydroxy-groups into the 24-, 25-, and 26-positions of the cholesterol side chain.This publication has 3 references indexed in Scilit:
- Configurational assignment of 5β-cholestane-3α, 7α, 12α, 23, 25-pentol excreted by patients with cerebrotendinous xanthomatosis (a circular dichroism study)Steroids, 1979
- Identification of bile alcohols in normal rabbit bileSteroids, 1978
- COMPARATIVE BIOCHEMICAL STUDIES OF BILE-ACIDS AND BILE ALCOHOLS .8. IDENTIFICATION OF 5BETA-CHOLESTANE-3ALPHA, 7ALPHA, 12ALPHA, 23BETA-TETROL, 5BETA-CHOLESTANE-3ALPHA, 7ALPHA, 12ALPHA-TETROL, AND 5BETA-CHOLESTANE-3ALPHA, 7ALPHA, 12ALPHA, 24BETA-TETROL IN CEREBROTENDINOUS XANTHOMATOSIS1978