Synthesis of a deoxyristomycinic acid derivative using organomanganese chemistry
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 2251-2254
- https://doi.org/10.1039/p19900002251
Abstract
Coupling of (3-chloro-2-methylanisole) tricarbonylmanganese tetrafluoroborate with the phenoxide derived from methyl N-Boc-3-hydroxyphenylglycinate gave the diaryl ether manganese complex (6). This complex underwent regiospecific, stereoselective reaction with Schollkopf's chiral glycine enolate equivalent to give a mixture of dienyl-Mn(CO)3 complexes that were converted in a two-step sequence into the protected deoxyristomycinic acid derivative (12).This publication has 4 references indexed in Scilit:
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