F and perturbed F(F*) centres in strontium chloride
- 21 April 1975
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 8 (8) , 1119-1124
- https://doi.org/10.1088/0022-3719/8/8/015
Abstract
Point-ion and ion-size calculations on F centres and F* centres (F centres perturbed by an alkaline impurity) in SrCl2 are described. The point-ion calculation for the F centre gives a transition energy of 2.11 eV (experiment 2.13 eV) and a hyperfine interaction with the hearest 35Cl nuclei of 45.7 MHz (experiment 23.8 MHz). Ion-size calculations lead to an improved value for the hyperfine interaction. A model of the F* centre with an interstitial alkali ion in a second-neighbour position and associated distortions explains the observed optical absorption spectra.Keywords
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