SYNTHESIS OF TRANS-4,8,12,15,15-PENTAMETHYLBICYCLO[9,3,1]PENTADECA-3E,7Z,12Z-TRIENE, A GEOMETRICAL ISOMER OF ANHYDROVERTICILLOL
- 5 January 1981
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (1) , 25-28
- https://doi.org/10.1246/cl.1981.25
Abstract
A 7Z-isomer of anhydroverticillol skeleton was constructed in 15% yield when the 7E allyl bromide having secoverticillol framework was treated with LiN(TMS)2. Reductive removal of the SO2Ph group furnished a geometrical isomer of anhydroverticillol.Keywords
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