Iridium(III) salts as homogeneous metal catalysts for hydrogen isotope exchange in organic compounds: a comparison with heterogeneous iridium for the deuteriation of alkylbenzenes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 749-750
- https://doi.org/10.1039/c39730000749
Abstract
Hydrogen exchange between organic compounds and heavy water is homogeneously catalysed by sodium chloroiridite; results for alkylbenzenes are compared with those from heterogeneous catalysis by iridium metal and are interpreted in terms of the role of π-complex intermediates.Keywords
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