Conversion of primary aliphatic amines into thiocyanates and thiocarbonate esters
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 133-134
- https://doi.org/10.1039/c39780000133
Abstract
2,4,6-Triphenylpyrylium thiocyanate converts primary aliphatic amines into 1-substituted-2,4,6-triphenylpyridinium thiocyanates which smoothly pyrolyse to 2,4,6-triphenylpyridine and the corresponding alkyl thiocyanate; 1-substituted-2,4,6 triphenylpyridinium perchlorates give S-alkyl O-ethyl dithiocarbonates with potassium ethyl xanthate.Keywords
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