Experimental studies of the spin-correlated radical pair in micellar and microemulsion media; MARY, RYDMRB0and RYDMRB1spectra
- 20 December 1988
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 65 (6) , 1483-1503
- https://doi.org/10.1080/00268978800101941
Abstract
The effects of static magnetic fields and resonant microwave fields on the reaction of spin-correlated radical pairs are reported in well-characterized micellar and microemulsion media, using MARY, RYDMR B 0 and RYDMR B 1 techniques in a new apparatus. Large field effects were observed and direct evidence was obtained for the influence of the electron exchange interaction on the results. The results of a theoretical analysis of the RYDMR lineshapes resulting from reaction of an initial triplet radical pair through a singlet reaction channel are presented.Keywords
This publication has 24 references indexed in Scilit:
- Spin-polarized electron paramagnetic resonance spectra of radical pairs in micelles: observation of electron spin-spin interactionsThe Journal of Physical Chemistry, 1987
- Electron spin resonance of spin-correlated radical pairsChemical Physics Letters, 1987
- Low-power, low-field RYDMAR of the primary radical pair in photosynthesisChemical Physics Letters, 1985
- An experimental method for the study of the effects of magnetic and microwave fields on radical recombination reactionsMolecular Physics, 1985
- Time-domain magnetic resonance studies of short-lived radical pairs in liquid solutionFaraday Discussions of the Chemical Society, 1984
- Nanosecond time-resolved magnetic resonance of the primary radical pair state PF of bacterial photosynthesisJournal of the American Chemical Society, 1983
- Optically detected time resolved epr of radical ion pairs in pulse radiolysis of liquidsChemical Physics Letters, 1980
- Optical detection of ESR absorption of short-lived ion-radical pairs produced in solution by ionizing radiationChemical Physics Letters, 1979
- Theory of magnetic field modulation of radical recombination reactions. III. Time dependent solutionChemical Physics, 1977
- Theory of the magnetic field modulated geminate recombination of radical ion pairs in polar solvents: Application to the pyrene–N,N-dimethylaniline systemThe Journal of Chemical Physics, 1977