ON THE SIDE REACTIONS ACCOMPANYING THE TRANS-ESTERIFICATION OF THE ACID DIESTERS OF PHOSPHOROUS ACID
- 1 May 1984
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 19 (3) , 363-367
- https://doi.org/10.1080/03086648408077600
Abstract
The side reaction accompanying the trans-esterification of the acid diesters of phosphorous acid is studied, leading to the formation of R[sbnd]O[sbnd]R type ethers, where R is the aliphatic group of the acid ester. The products of the side reaction are identified by 1H and 13C-NMR spectroscopy. It is shown that the R[sbnd]O[sbnd]R ether is formed as a result of the pyrolysis of dimethyl phosphite.Keywords
This publication has 1 reference indexed in Scilit:
- Pyrolysis of Dimethyl Hydrogen PhosphiteI&EC Product Research and Development, 1963