Pseudo-rotation in seven-co-ordination: implications in catalysis. X-Ray crystal structure of [HMo(C2H4)2(cis-Ph2PCHCHPPh2)2]+
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 662-663
- https://doi.org/10.1039/c39770000662
Abstract
The seven-co-ordinate complex, [HMo(C2H4)2-(cis-Ph2PCHCHPPh2)]+, is pentagonal bipyramidal both in solution and in the solid state, and undergoes internal rearrangement by a pseudo-rotation process.Keywords
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