Catalytic conversions in water: 17O, {1H}31P and 35Cl NMR study of a novel stoichiometric redox reaction between PdCl2, tppts and H2O [tppts = P(C6H4-m-SO3Na)3]
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1105-1106
- https://doi.org/10.1039/c39950001105
Abstract
17 O, {1H}31P and 35Cl NMR are used to investigate the mechanism of the reaction of PdCl2 with tppts [tppts = P(C6H4-m-SO3Na)3] in 17O enriched water to give the novel complex [PdCl(tppts)3]+1, which is reduced quantitatively to Pd(tppts)32 with tppts (8 d, 25 °C); with CO (2 bar) reduction to 2 is quantitative in 5 min at 25 °C.Keywords
This publication has 0 references indexed in Scilit: