Theorem on the Mobile Bond Orders of Alternant Conjugated Systems
- 1 December 1958
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 29 (6) , 1232-1233
- https://doi.org/10.1063/1.1744703
Abstract
A generalization of Hall's theorem for Coulson bond orders in alternant molecules is derived. The new relation expresses general bond order‐like quantities in terms of the topological molecular matrix. Specialization to the Mulliken bond orders furnishes an exact relation between the Coulson and the Mulliken bond order matrices in the ground state of alternants.Keywords
This publication has 2 references indexed in Scilit:
- Mobile Bond Orders in Conjugated SystemsThe Journal of Chemical Physics, 1958
- Free-Electron Network Model for Conjugated Systems. I. TheoryThe Journal of Chemical Physics, 1953