Effective ruthenium-catalysed oxidation of chlorinated olefins by monopersulfate in aqueous medium
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 253-254
- https://doi.org/10.1039/c39940000253
Abstract
In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes α-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min–1 at room temperature.Keywords
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