Cobalt(II) Porphyrin-Catalyzed Oxidation of Olefins to Ketones with Molecular Oxygen and Triethylsilane in 2-Propanol
- 1 July 1992
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 21 (7) , 1381-1384
- https://doi.org/10.1246/cl.1992.1381
Abstract
An efficient conversion of olefins to ketones was achieved by the use of molecular oxygen and triethylsilane in the presence of a catalytic amount of cobalt(II) complex of porphyrin. The oxidation was accelerated remarkably in alcohols and had chemoselectivity for conjugated olefins.Keywords
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