Palladium-catalysed borylsilylation and borylstannylative dimerization of 1,2-dienes
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 1863-1864
- https://doi.org/10.1039/a905127i
Abstract
A borylsilane regioselectively adds to 1,2-dienes in the presence of palladium complexes to afford high yields of alkenylboranes having allylsilane moieties, whereas a borylstannane gives a 1 : 2 telomer with 3-methylbuta-1,2-diene due to borylstannylative dimerization.Keywords
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