Biosynthesis of natural products. Part 1. Incorporations of ent-kaur-16-ene and ent-kaur-16-en-15-one into enmein and oridonin
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 19,p. 2098-2102
- https://doi.org/10.1039/p19760002098
Abstract
Incorporations of ent-kaur-16-ene (7a) and ent-kaur-16-en-15-one (14a) into enmein (1a) and oridonin (6a) by Isodon japonicus Hara have been demonstrated by tracer experiments with seven labelled ent-kaurene derivatives. Furthermore, evidence has been obtained that functionalisation of ent-kaur-16-ene at the allylic position C–15 proceeds through direct oxygenation.This publication has 4 references indexed in Scilit:
- Biosynthesis of steviol from (−)-kaurenePhytochemistry, 1967
- Effect of Photoperiodic Floral Induction on the Metabolism of a Gibberellin Precursor, (-)-Kaurene, in Pharbitis nilPlant Physiology, 1966
- Constitution and stereochemistry of enmein, a diterpene from isodon trichocarpus kudoTetrahedron, 1966
- Terpenoids—IITetrahedron, 1966