The isolation and X-ray crystal structure of an adduct formed between 18-crown-6 and cisplatin
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 532-533
- https://doi.org/10.1039/c39850000532
Abstract
The X-ray structure of the crystalline complex formed between 18-crown-6 and 2 mol. equiv. of cisplatin and dimethylacetamide reveals hydrogen bonding which involves all three hydrogen atoms on both ammine ligands of cisplatin forming bonds to (i) all six oxygen atoms of 18-crown-6, (ii)one chlorine atom on a symmetry-translated cisplatin, and (iii)the carbonyl oxygen atom of dimethylacetamide.Keywords
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