Hydroperoxides as pseudohalides: oxidation, oxidative alkylation, acylation and arylation of acrylonitrile

1 January 1995

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 14,p. 1399-1400
https://doi.org/10.1039/c39950001399

Abstract

New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of Bu^tO₂H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.

Keywords

PSEUDOHALIDES
HYDROPEROXIDES
PEROXY
RADICAL
BUTO2H
SYNTHESES
OXIDATIVE ALKYLATION
ACYLATION AND ARYLATION

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