Scaling for first-order phase transitions in thermodynamic and finite systems
- 1 September 1982
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 26 (5) , 2507-2513
- https://doi.org/10.1103/physrevb.26.2507
Abstract
Scaling behavior for first-order phase transitions can be derived alternatively but consistently from renormalization-group, phenomenological, or finite-size considerations. A general analysis of densities at a renormalization-group fixed point demonstrates that if the coexistence of distinct phases is possible, then distinct eigenvalue exponents must equal the spatial dimensionality. This basic eigenvalue (or scaling) exponent condition can also be derived phenomenologically by various arguments not depending on detailed renormalization-group considerations. A scaling description of first-order phase transitions is presented and extended to finite systems with linear dimensions , leading to a rounding proportional to , response-function maxima varying as , and boundary-condition-dependent shifts which may be as large as .
Keywords
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