Synthesis and crystal and molecular structure of (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,IIImixed-valence cluster with the decametallate core geometry
- 1 January 1993
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 131-133
- https://doi.org/10.1039/c39930000131
Abstract
The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.Keywords
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