X-Ray determination of molecular structures of molybdenum(IV) oxo-complexes. The possibility of a new type of isomerism
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 13,p. 655-656
- https://doi.org/10.1039/c29710000655
Abstract
Notable differences between corresponding bond lengths and interbond angles in the complexes blue cis-mer-[MoOCl2(PMe2(Ph)3] and green cis-mer-[MoOCl2(PEt2Ph)3] are caused by ligand repulsions; an explanation of the isomerism of mer-[MoOCl2(PMe2Ph)3] is suggested in terms of the structures of the above complexes.Keywords
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