HIGHLY STRUCTURE-CONFINED Y:Ba:Cu:O SUPERCONDUCTORS PREPARED BY COPRECIPITATION TECHNIQUES

Abstract
Results from the study of highly structure-confined YBa 2 Cu 3 O 7−x superconductors synthesized by different coprecipitation processes are presented, with the superconducting samples made from oxalic-nitrate salts demonstrating higher critical temperature and critical current in comparison with solid reaction oxides. Among the measured samples, the critical temperature, T c , is typically 90–95 K (T c (maximum)=105 K) and the critical current is 1.2 – 1.9 × 104 A/cm 2 at 4.5 K and 1200 A/cm 2 at 78 K. Peak patterns similar to those of solid-state reactions by X-ray diffraction analysis have also been found although these spectra show considerably broadness. Superconductors resulted from coprecipitation techniques with no calcining (heat-treatment) processing can be attained. Further studies on producing single-crystal with increasing critical current and temperature are discussed.

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