Delayed-detection measurement of atomic Na 3p2P3/2hyperfine structure using polarization quantum-beat spectroscopy

Abstract
A subnatural linewidth measurement of magnetic-dipole and electric-quadrupole hyperfine coupling constants in the atomic Na 3p 2 P3/2 level are reported. The measurements are made using a pump–delayed-probe method, with delays ranging to 135 ns, more than eight times the natural lifetime of the 3p 2 P3/2 level. A measurement of hyperfine-induced beats in the time evolution of the electronic alignment permitted determination of the hyperfine frequencies to well beyond the natural width in that level. Hyperfine coupling constants A=18.534(15) MHz and B=2.724(30) MHz are obtained, these being more than 2 times more precise than any previous determination of those quantities.