Mass spectrometry of methyltetrazoles
- 1 May 1969
- journal article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 2 (5) , 433-445
- https://doi.org/10.1002/oms.1210020502
Abstract
The mass spectra of tetrazole, all isomers of monomethyl‐ and dimethyltetrazole, several trifluoromethyl substituted tetrazoles, as well as deuterated analogs, were recorded. Loss of N2 was the important fragmentation of the molecular ions of tetrazole and 2‐methyl substituted tetrazoles; however, HN2 loss was more important for 1‐methyl substituted tetrazoles. The 1‐methyl‐tetrazoles showed molecular ion peaks while the 2‐methyltetrazoles exhibited an unprecedented [M + 1] peak with no molecular ion.Keywords
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