Solvent transfer hydrogenation of αβ-unsaturated aldehydes to the unsaturated alcohols catalysed by hydridoiridium sulphoxide complexes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 929-930
- https://doi.org/10.1039/c39780000929
Abstract
The unusual selective hydrogenation of αβ-unsaturated aldehydes to the unsaturated alcohols has been accomplished catalytically under mild conditions using the iridium complex HIrCl2(Me2SO)3 in propan-2-ol, the solvent being the source of hydrogen.Keywords
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