EXCHANGE REACTION BETWEEN HPO42− AND C6H5OPO32− IN A HETEROGENEOUS SYSTEM WITH γ-ZIRCONIUM PHOSPHATE, Zr(HPO4)2·2H2O
- 5 September 1979
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 8 (9) , 1073-1076
- https://doi.org/10.1246/cl.1979.1073
Abstract
The monohydrogen orthophosphate ions on the interlayer surfaces of a cation exchanger γ-zirconium phosphate, Zr(HPO4)2·2H2O, are exchanged with monophenyl orthophosphate ions of the external solution, and a new type of compound Zr(C6H5OPO3)(HPO4)·2H2O is formed. The exchange is reversible. The compound reverts to the initial γ-zirconium phosphate in orthophosphoric acid solutions.Keywords
This publication has 5 references indexed in Scilit:
- Formation region and structural model of γ-zirconium phosphateJournal of Inorganic and Nuclear Chemistry, 1979
- Synthesis of the organic derivatives of γ-zirconium phosphate by the reaction with propylene oxideJournal of Inorganic and Nuclear Chemistry, 1979
- Uptake of pyridine and n-butylamine by crystalline zirconium phosphateJournal of Inorganic and Nuclear Chemistry, 1976
- Synthesis and characterization of the organic derivatives of zirconium phosphateInorganic Chemistry, 1976
- New crystalline phases of zirconium phosphate possessing ion-exchange propertiesJournal of Inorganic and Nuclear Chemistry, 1968