Triple-stranded helices and zigzag chains of copper(i) 2-ethylimidazolate: solvent polarity-induced supramolecular isomerism
- 9 March 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 2232-2234
- https://doi.org/10.1039/b501071c
Abstract
The solvent effect of different polarities in hydro(solvo)thermal reaction of CuII and 2-ethylimidazole leads to the generation of two supramolecular isomers of triple-stranded helical and zigzag chain-like structures of CuI 2-ethylimidazolate.Keywords
This publication has 25 references indexed in Scilit:
- Reaction‐Temperature‐Dependent Supramolecular Isomerism of Coordination Networks Based on the Organometallic Building Block [CuI2(μ2‐BQ)(μ2‐OAc)2]Angewandte Chemie International Edition in English, 2004
- [Ni2O(l-Asp)(H2O)2]·4H2O: A Homochiral 1D Helical Chain Hybrid Compound with Extended Ni−O−Ni BondingJournal of the American Chemical Society, 2004
- Spontaneous chiral resolution of a coordination polymer with distorted helical structure consisting of achiral building blocksDedicated to Professor Peter Jutzi on the occasion of his 65th birthday.Chemical Communications, 2003
- A homochiral triple helix constructed from an axially chiral bipyridineElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b212781d/Chemical Communications, 2003
- Reactions of Triazacyclohexanes with CuCl2: Surprising Formation of a Dimer between Two [CuCl2]− Ions with an Unsupported Cuprophilic AttractionAngewandte Chemie International Edition in English, 2003
- Cryptic crystallographyNature Materials, 2002
- α- and β-Bis(1,1,1-trifluoro-5,5-dimethyl-5-methoxyacetylacetonato)copper(II): Transforming the Dense Polymorph into a Versatile New Microporous FrameworkJournal of the American Chemical Society, 1999
- Helical Coordination Polymers from Achiral Components in Crystals. Homochiral Crystallization, Homochiral Helix Winding in the Solid State, and Chirality Control by SeedingJournal of the American Chemical Society, 1999
- Luminescent polynuclear d10 metal complexesChemical Society Reviews, 1999
- Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO3)2(1,2‐bis(4‐pyridyl)ethane)1.5]nAngewandte Chemie International Edition in English, 1997